Neutron Activation Analysis at Gordion:
Ceramics and Clays

In collaboration with M. J. Blackman, an ongoing program of chemical analysis of Gordion pottery and local clay samples is being carried out by instrumental neutron activation analysis (INAA) in the Smithsonian Center for Materials Research and Education facility, using the 20 MW NBS Research Reactor at the National Institute of Standards and Technology. The analytical protocol is a modification of that outlined by Blackman (1984). Williams et al. (1987) had previously compared the pastes of local Hellenistic grey ware pottery with that of imported Hellenistic Black Glazed ware using PIXE [Proton-Induced X-ray Emission] analysis.

The current program is providing data on both the nature and possible extent of local production at Gordion and the changing patterns of local resource exploitation.

Sampling

Pottery Samples

All pottery samples have been chosen, when possible, from clearly defined and securely dated contexts which represent relatively brief depositional episodes. Most derive from trash deposits on floors or in pits. Sampling concentrated on the predominant ware from each period:

Predominant Wares by YHSS Period
YHSS Period
Ware
Approximate Dates
YHSS 2: Roman Buff Fine 1st cent. BC - 3rd cent. AD
YHSS 3: Hellenistic Grey Common
Ca. 330-189 BC
YHSS 6-4: Early - Late Phrygian Grey Common
950-330 BC
YHSS 7: Early Iron Age Handmade
and
Buff Common
1200-950 BC
YHSS 10-8: Middle-Late Bronze Age
Buff Common
1500-1200 BC

Phrygian-era (YHSS 6-3) Ware Descriptions

Basic Bronze and Early Iron (YHSS 10-7) Ware Descriptions

Limited sampling of minor wares (e.g., Buff Fine and Cooking wares in the Late Bronze Age and finer grey and buff wares in Phrygian periods) has begun exploring the variability among wares within single periods.

In two cases it has been possible to sample individual vessels, representing most contemporary ware and vessel types, from very tightly dated and stratigraphically discrete deposits:

Sampling of Individual Vessels
YHSS Period
Context
Number of Vessels
Approximate Date
YHSS 5: Middle Phrygian Trash deposit
92
ca. 550 BC
YHSS 6[A]: Early Phrygian Vessels on floor,
in Destruction Level
77
end of 8th cent. BC

Samples from architectural terracottas, particularly 29 tiles from the roof of one Hellenistic building (Galatian phase, YHSS 3A), have also been run (Henrickson and Blackman 1999; see Hellenistic Tile Roof).

All ceramic samples were prepared by grinding away all surfaces and edges before crushing to a fine powder in a mortar. Samples of 100±5 mg were packaged for activation.

Clay Samples

Clays from both ancient and modern deposits were sampled to define the nature of clay resources available and to determine whether changes might have occurred over time. Samples come from two sources: natural deposits surrounding Gordion and massive clay construction fills on the Citadel Mound. Shrinkage and workability tests confirmed that almost all of the clays sampled were potentially usable for pottery production, even without preparation (see also Johnston 1970). At present, only clays from the Sakarya River drainage have been sampled; two other nearby streams (the Ankara and Porsuk Çay) remain untested.
 

Photo: View across alluvial plain to Citadel Mound
View across flood plain to Citadel Mound.
River and Flood Plain Samples. Extensive and deep (4 m or more) post-Roman alluviation derived from Sakarya River overbank flooding has buried the ancient valley floor; these floodplain deposits are primarily calcareous grey silts and clays. Samples from the Sakarya River banks and from several localities on the plain are thus likely post-Roman (Marsh in Voigt et al.). Several exposures of pre-Phrygian natural clay deposits have also sampled. INAA results show that both recently deposited sediments and those in situ in antiquity are similar in composition.
Photo: Sakarya streambank
Sakarya: long view downstream
to cutbank.
Photo: Sakarya streambank
Sakarya: medium view downstream
to cutbank.
Photo: Sakarya streambank
Closeup of cutbank
with pre-Phrygian clay
at water level.
Photo: Sakarya streambank
View further downstream,
with Hellenistic deposit
eroding at base of bank.
Photo: View of Operation 2 trench
Clay fill layer in Operation 2
(above stone wall and
below stone pavement in baulk).
Clay Samples from Phrygian Construction Fills. Most clay samples used in this study come from massive eighth and seventh centuries BC construction fills used to create terraces on the City Mound. The relatively clean clays and silts making up these fills contain little or no cultural material. They range in color from off-white through greys to brown to red-brown and in texture from clayey to silty.They provide samples of material available in antiquity. The fills marking the beginning of the Middle Phrygian (YHSS 5) rebuilding program, with 1-5 m of clay and silts laid over much of the 8-10 ha area of the Citadel mound contain 100,000 - 200,000 m3 or even more. Sheer volume alone suggests that the material came from near the city. Wilkinson and Marsh have suggested that much is spoil from channelization of the river and related irrigation projects.

These clay samples from fills provide critical data on potential 'local' raw materials, available near the settlement, during the Phrygian florescence in the second quarter of the first millennium BC.

Clay Sample Preparation. Preparation and firing temperature have crucial effects on the long-term durability of a ceramic fabric made using calcareous clays. Decomposition of calcium carbonate (CaCO3: limestone, calcite, or shell) into lime (CaO) occurs over a range of temperature, beginning at ±800 C and accelerating at 870-900 C; its pace depends on grain size, purity, and the partial pressure of CO2. Rehydration of the lime causes expansion, producing cracking, spalling, or disintegration of the ceramic fabric. In order to improve comparability between the clay samples and ceramics, two unaltered lumps (1-2 cm in diameter) of each clay sample were fired for one hour at 650 C and 850 C in an oxidizing atmosphere. These bracket the temperature at which carbonate decomposition occurs and represent the range of original firing temperatures for common wares as estimated from refiring experiments.

INAA Samples Run, By YHSS Period
YHSS Period
Samples Run
Approximate Dates
1: Medieval
0
10-12th cent. AD
2: Roman
15
1st cent. BC - 3rd cent. AD
3: Hellenistic
32
Late 4th century - 189 BC
4: Late Phrygian / Persian
73
550-330 BC
5: Middle Phrygian
222
700-550 BC
6: Early Phrygian
159
950-700 BC
7: Early Iron Age
118
1100-950 BC
9-8: Late Bronze Age
109
1500-1200 BC
10: Middle Bronze Age
54
1500-1600 BC

Total Ceramic Samples

781

Middle Bronze to Roman

Ancient and Modern Clay
Fired Samples

119

Pre-Phrygian to Modern

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Related Bibliography

Blackman, M. James

1984 "Provenance Studies of Middle Eastern Obsidian from Sites in Highland Iran." In Archaeological Chemistry, pp. 19-50, edited by J. Lambert. American Chemical Society.

Henrickson, Robert C., and Blackman, M. James.

1996 "Large-Scale Production of Pottery at Gordion: A Comparison of the Late Bronze and Early Phrygian Industries" Paleorient 22(1): 67-87.

1999 "Hellenistic Production of Terracotta Roof Tiles Among the Ceramic Industries at Gordion". Oxford Journal of Archaeology 18(3): 307-326.

In prep. "The Early Iron Age Pottery Industries at Gordion: A Technological and Compositional Investigation of Interrelationships". To be submitted to Journal of Mediterranean Archaeology.

In prep. "Pots, Pastes, and Production Methods: Continuity and Change between the Early and Middle Phrygian Pottery Industries at Gordion."

Henrickson, Robert C., and Voigt, Mary M.
1998 "The Early Iron Age at Gordion: The Yassihöyük Stratigraphic Sequence." Pp. 79-107 in Thracians and Phrygians: Problems of Parallelism (Proceedings of an International Symposium on the Archaeology, History, and Ancient Languages of Thrace and Phrygia [Middle East Technical University, Ankara, Turkey, 2-6 June 1995]), edited by Numan Tuna, Zeynep Aktüre, and Maggie Lynch. Centre for the Research and Assessment of the Historic Environment. Ankara: Middle Eastern Technical University (METU), Faculty of Architecture Press.

Johnston, Robert H.

1970 Pottery Practices During the 6th-8th Centuries B.C. at Gordion in Central Anatolia: An Analytical and Synthesizing Study.Ph. D. dissertation, Pennsylvania State University.

Voigt, Mary M.; DeVries, K.; Henrickson, R. C.; Lawall, M.; Marsh, D.; Gürsan-Salzman, A.; and Young, T. C.,Jr.

1997 "Fieldwork at Gordion: 1993-1995." Anatolica (Annuaire international pour les Civilisations de l'Asie Antérieure) 23: 1-59.

Voigt, Mary M., and Henrickson, Robert C.

In press "The Early Iron Age at Gordion." To be published in Peoples of the Sea, edited by E. Oren and L. Bregstein. University Museum Monograph. Philadephia: University of Pennsylvania Museum of Archaeology and Anthropology.

In press "Gordion -- The Formation of the Phrygian State" To be published in Anatolian Studies 50 (2000).

Williams, E. T.; Cadet, G.; Guardala, N. A.; Huang, E; and Winter, F. A.

1987 "Analysis of Pottery by PIXE: Late Classical and Hellenistic Imports to Gordion. Nuclear Instruments and Methods in Physics Research B22: 430-432.


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Last Revised: 17 October 2000

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© 2000 R. C. Henrickson